Rabu, 19 Desember 2012


13.1 Introduction

Petroleum (also called crude oil), in the unrefined or crude form, like many industrial feedstocks has little or no direct use and its value as an industrial commodity is only realized after the production of salable products. Even then, the market demand dictates the type of products that are needed. Therefore, the value of petroleum is directly related to the yield of products and is subject to the call of the market.

As the basic elements of crude oil, hydrogen and carbon form the main input into a refinery, combining into thousands of individual constituents, and the economic recovery of these constituents varies with the individual petroleum according to its particular individual qualities, and the processing facilities of a particular refinery (Fig. 13.1). In general, crude oil, once refined, yields three basic groupings of products that are produced when it is broken down into cuts or fractions (Table 13.1).


The gas and gasoline cuts form the lower boiling products and are usually more valuable than the higher boiling fractions and provide gas (liquefied petroleum gas), naphtha, aviation fuel, motor fuel, and feedstocks, for the petrochemical industry. Naphtha, a precursor to gasoline and solvents, is extracted from both the light and middle range of distillate cuts and is also used as a feedstock for the petrochemical industry. The middle distillates refer to products from the middle boiling range of petroleum and include kerosene, diesel fuel, distillate fuel oil, and light gas oil; waxy distillate and lower boiling lubricating oils are sometimes included in the middle distillates. The remainder of the crude oil includes the higher boiling lubricating oils, gas oil, and residuum (the nonvolatile fraction of the crude oil). The residuum can also produce heavy lubricating oils and waxes but is more often used for asphalt production. The complexity of petroleum is emphasized insofar as the actual proportions of light, medium, and heavy fractions vary significantly from one crude oil to another.

In the early days of petroleum refining, the first processes were developed to extract kerosene for lamps. Any other products were considered to be unusable and were usually discarded. Thus, the first refining processes were developed to purify, stabilize, and improve the quality of kerosene. However, the invention of the internal combustion engine led (at about the time of World War I) to a demand for gasoline for use in increasing quantities as a motor fuel for cars and trucks. This demand on the lower boiling products increased, particularly when the market for aviation fuel developed. Thereafter, refining methods had to be constantly adapted and improved to meet the quality requirements and needs of car and aircraft engines.

Since then, the general trend throughout refining has been to produce more products from each barrel of petroleum and to process those products in different ways to meet the product specifications for use in modern engines. Overall, the demand for gasoline has rapidly expanded and demand has also developed for gas oils and fuels for domestic central heating, and fuel oil for power generation, as well as for light distillates and other inputs, derived from crude oil, for the petrochemical industries. 

As the need for the lower boiling products developed, petroleum yielding the desired quantities of the lower boiling products became less available and refineries had to introduce conversion processes to produce greater quantities of lighter products from the higher boiling fractions. The means by which a refinery operates in terms of producing the relevant products depends not only on the nature of the petroleum feedstock but also on its configuration (i.e., the number of types of the processes that are employed to produce the desired product, slate) and the refinery configuration is, therefore, influenced by the specific demands of a market. Therefore, refineries need to be constantly adapted and upgraded to remain viable and responsive to the ever-changing patterns of crude supply and product market demands. As a result, refineries have been introducing increasingly complex and expensive processes to gain more and more lower-boiling products from the heavier and residual ends of a barrel.

To convert crude oil into desired products in an economically feasible and environmentally acceptable manner. Refinery processes for crude oil are generally divided into three categories: (1) separation processes, of which distillation is the prime example, (2) conversion processes, of which coking and catalytic cracking are prime examples, and (3) finishing processes, of which hydrotreating to remove sulfur is a prime example. However, before separation of petroleum into its various constituents can proceed, there is the need to clean the petroleum. This is often referred to as desalting and dewatering in which the goal is to remove water and the constituents of the brine that accompany the crude oil from the reservoir to the wellhead during recovery operations.



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